Short but useless answer -- yes, I'm sure there is a way to add a single data point.
So much of charting seems to be about the way you arrange data in the spreadsheet. Where are you putting the data point for the 3rd data series? Where are the data for the other 2 data series? My first expectation would be something like:
Put the data point in the row where you want the benchmark point to be. This third series should be added as a line chart type and should probably be formatted as markers without lines.
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