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Here's another way, assuming total amounts are in column B:
Formula:100s =ROUNDDOWN($B2/100,0)
20s =ROUNDDOWN(MOD($B2,100)/20,0)
10s =ROUNDDOWN(MOD(MOD($B2,100),20)/10,0)
5s =ROUNDDOWN(MOD(MOD(MOD($B2,100),20),10)/5,0)
1s =ROUNDDOWN(MOD(MOD(MOD(MOD($B2,100),20),10),5)/1,0)
Copy down as far as you need.
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